Properties of paper

Paper is made of cellulose fibres. These fibres are hygroscopic which means they ‘suck’ moisture from the surrounding atmosphere. Water has the effect of ‘plasticising’ the cellulose fibres, which is another word for weakening them. Ordinary paper, when wet, has very little strength. The inter-fibre bonds relax, so weakening the sheet. Toilet tissue can claim ‘wet-strength’ if it has just 15% of its strength remaining when it is saturated.

A book has to adapt to its environment and in the process can change shape. If you live in a northern climate, have a look at the map you keep in the car. The high humidity normally encountered in cars makes the pages swell and buckle.

One symptom that is frequently observed is ‘cockling’. Cockling is the wrinkled or puckered condition found in a sheet of paper or board and is caused by non-uniform drying and shrinkage. When a book comes from the printers, the pages can often develop ‘waves’ in the pages. Printers go to great lengths to ensure that paper is exactly the right size so that the images are all in precisely the right place on the sheets they print. Some print processes even allow for spraying a fine mist onto the surface of the paper to ensure the correct dimensions.

A book normally adjusts within a week to domestic conditions and the cockling vanishes. However it is worth storing the book flat while it is making this adjustment.

Cockling is magnified if the grain of the paper is not parallel to the binding edge. Paper expands more across the grain, and with machine-made papers the width to length expansion ratio can be 10:1. A typical piece of paper will expand by 1-2% when wet.

Paper benefits from a small percentage of moisture. The moisture content in paper varies from 2-12% depending on the type of pulp and processing used, the degree of refining and the chemicals used. A ‘normal’ water content is between 5 and 7 percent by weight. A sheet of wet paper might contain 20% moisture.
 

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